Document Details
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Document Type |
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Article In Journal |
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Document Title |
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Dichlorido[(4E,11E)-5,7,12,14-tetra-benzyl-7,14-dimethyl-1,4,8, 11-tetra-aza-cyclo-tetra-deca-4,11-diene]cobalt(III) perchlorate Dichlorido[(4E,11E)-5,7,12,14-tetra-benzyl-7,14-dimethyl-1,4,8, 11-tetra-aza-cyclo-tetra-deca-4,11-diene]cobalt(III) perchlorate |
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Subject |
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Chemistry |
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Document Language |
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English |
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Abstract |
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The CoIII atom in the title complex, [CoCl2(C 40H48N4)]ClO4, is octa-hedrally coordinated within a trans-Cl2N4 donor set provided by the tetra-dentate macrocylic ligand and two chloride ions. The N - H atoms, which are orientated to one side of the N4 plane, form hydrogen bonds with chloride ions and perchlorate-O atoms. These along with C - H⋯O interactions consolidate the three-dimensional crystal structure. One of the benzene rings was disordered. This was resolved over two positions with the major component of the disorder having a site-occupancy factor of 0.672 (4). |
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ISSN |
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1600-5368 |
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Journal Name |
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Acta Crystallographica Section E: Structure Reports Online |
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Volume |
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67 |
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Issue Number |
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12 |
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Publishing Year |
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1432 AH
2011 AD |
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Article Type |
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Article |
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Added Date |
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Tuesday, January 3, 2012 |
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Researchers
| T G Roy | Roy, T G | Researcher | Doctorate | tapashir@yahoo.com |
| S K S Hazari | Hazari, S K S | Researcher | Doctorate | |
| K K Barua | Barua, K K | Researcher | Doctorate | |
| Seik Weng Ng | Ng, Seik Weng | Researcher | Doctorate | seikweng@um.edu.my |
| E R T Tiekink | Tiekink, E R T | Researcher | Doctorate | edward.tiekink@gmail.com |
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